西藏西南部达巴-休古嘎布蛇绿岩带中地幔橄榄岩的成因   总被引：11，自引：0，他引：11  

徐德明  黄圭成  黄陵勤  雷义均  李丽娟 《华南地质与矿产》2006,(3):10-18

本文报道了西藏西南部达巴-休古嘎布蛇绿岩带中橄榄岩的矿物化学资料.橄榄岩中主要造岩矿物化学成分的分析研究表明,该区橄榄岩为残余地幔成因,但它们不是地幔简单熔化的残余物.尖晶石中Cr#及辉石中Ti的广泛变化表明它们具有复杂的熔融历史及地幔交代作用的印记,其形成过程可能经历了两种构造环境的转变.早期在MORB环境下形成低Cr#(尖晶石)橄榄岩;其后由于洋内俯冲作用,早先形成的低熔橄榄岩被消减到岛弧之下再度发生熔融形成高Cr#(尖晶石)橄榄岩.从而,在古大洋消失之后形成的碰撞带上同时保存了MORB型和SSZ型两类蛇绿岩.  相似文献   

Formation of diamond with mineral inclusions of “mixed” eclogite and peridotite paragenesis     

Wuyi Wang   《Earth and Planetary Science Letters》1998,160(3-4):831-843

Two unusual diamonds were studied from kimberlites from China, which contain both ultramafic and eclogitic mineral inclusions in the same diamond hosts. Diamond L32 contains seven Fe-rich garnets, four omphacites and one olivine inclusion. Four olivine, one sanidine and one coesite were recovered from diamond S32. Both garnet and omphacite inclusions have similar compositions as those from other localities of the world, and show basaltic bulk composition. All the garnet and omphacite inclusions in diamond L32 have positive Eu anomalies (Eu/Eu^*1.64 1.79). These observations support the proposal that mantle eclogite is the metamorphic product of subducted ancient oceanic crust. The Mg/(Mg + Fe) ratio of the olivine inclusions from the two diamonds (91-92) are evidently lower than the normal olivine inclusions in diamonds from the same kimberlite pipe (92-95). The following model is proposed for the formation of diamonds with “mixed” mineral inclusions. Ascending diamond-bearing eclogite (recycled oceanic crust) entrained in mantle plumes may experience extensive partial melting, whereas the ambient peridotite matrix remains subsolidus in the diamond stable field. This provides a mechanism for the transport of diamond from its original eclogitic host to an ultramafic one. Subsequent re-growth of diamond in the new environment makes it possible to capture mineral inclusions of different lithological suites. Partial melts of basaltic sources may interact with the surrounding peridotite, resulting in the relatively lower Mg/(Mg + Fe) ratios of the coexisting olivine inclusions from the studied diamonds. Diamonds with “mixed” mineral inclusions demonstrate that plume activity also occurred in the Archean cratons.  相似文献   

Bulk-rock Major and Trace Element Compositions of Abyssal Peridotites: Implications for Mantle Melting, Melt Extraction and Post-melting Processes Beneath Mid-Ocean Ridges   总被引：26，自引：2，他引：24  

NIU  YAOLING 《Journal of Petrology》2004,45(12):2423-2458

This paper presents the first comprehensive major and traceelement data for 130 abyssal peridotite samples from the Pacificand Indian ocean ridge–transform systems. The data revealimportant features about the petrogenesis of these rocks, mantlemelting and melt extraction processes beneath ocean ridges,and elemental behaviours. Although abyssal peridotites are serpentinized,and have also experienced seafloor weathering, magmatic signaturesremain well preserved in the bulk-rock compositions. The betterinverse correlation of MgO with progressively heavier rare earthelements (REE) reflects varying amounts of melt depletion. Thismelt depletion may result from recent sub-ridge mantle melting,but could also be inherited from previous melt extraction eventsfrom the fertile mantle source. Light REE (LREE) in bulk-rocksamples are more enriched, not more depleted, than in the constituentclinopyroxenes (cpx) of the same sample suites. If the cpx LREErecord sub-ridge mantle melting processes, then the bulk-rockLREE must reflect post-melting refertilization. The significantcorrelations of LREE (e.g. La, Ce, Pr, Nd) with immobile highfield strength elements (HFSE, e.g. Nb and Zr) suggest thatenrichments of both LREE and HFSE resulted from a common magmaticprocess. The refertilization takes place in the ‘cold’thermal boundary layer (TBL) beneath ridges through which theascending melts migrate and interact with the advanced residues.The refertilization apparently did not affect the cpx relicsanalyzed for trace elements. This observation suggests grain-boundaryporous melt migration in the TBL. The ascending melts may notbe thermally ‘reactive’, and thus may have affectedonly cpx rims, which, together with precipitated olivine, entrappedmelt, and the rest of the rock, were subsequently serpentinized.Very large variations in bulk-rock Zr/Hf and Nb/Ta ratios areobserved, which are unexpected. The correlation between thetwo ratios is consistent with observations on basalts that D_Zr/D_Hf< 1 and D_Nb/D_Ta < 1. Given the identical charges (5⁺ forNb and Ta; 4⁺ for Zr and Hf) and essentially the same ionicradii (R_Nb/R_Ta = 1·000 and R_Zr/R_Hf = 1·006–1·026),yet a factor of 2 mass differences (M_Zr/M_Hf = 0·511 andM_Nb/M_Ta = 0·513), it is hypothesized that mass-dependentD values, or diffusion or mass-transfer rates may be importantin causing elemental fractionations during porous melt migrationin the TBL. It is also possible that some ‘exotic’phases with highly fractionated Zr/Hf and Nb/Ta ratios may existin these rocks, thus having ‘nugget’ effects onthe bulk-rock analyses. All these hypotheses need testing byconstraining the storage and distribution of all the incompatibletrace elements in mantle peridotite. As serpentine containsup to 13 wt % H₂O, and is stable up to 7 GPa before it is transformedto dense hydrous magnesium silicate phases that are stable atpressures of 5–50 GPa, it is possible that the serpentinizedperidotites may survive, at least partly, subduction-zone dehydration,and transport large amounts of H₂O (also Ba, Rb, Cs, K, U, Sr,Pb, etc. with elevated U/Pb ratios) into the deep mantle. Thelatter may contribute to the HIMU component in the source regionsof some oceanic basalts. KEY WORDS: abyssal peridotites; serpentinization; seafloor weathering; bulk-rock major and trace element compositions; mantle melting; melt extraction; melt–residue interaction; porous flows; Nb/Ta and Zr/Hf fractionations; HIMU mantle sources  相似文献   

论高岭石粘土和铝土矿研究的新进展   总被引：4，自引：0，他引：4  

刘长龄 《沉积学报》2005,23(3):467-474

过去我国地质界向前苏联学习,把球粘土(Ballclay)作为高岭土或耐火粘土的一个变种,使我们找矿走入误区,以致后来从美国进口球粘土。其实球粘土的结晶性质这个内在因素与高岭土或耐火粘土常不相同,则派生的性能更不一样,应成为独立的矿种,还可与国际接轨。又过去国内外学者认为高岭石高度有序为热液型的,而沉积型的为无序高岭石。但笔者等的研究,我国高岭石高度有序而规模大且均匀稳定的,应算沉积型的紫矸(古生代高岭石软质粘土),可以作流动性好的造纸涂料。又我国硬水铝石岩溶铝土矿,应属于生物有机质成矿作用的沉积型铝土矿。  相似文献   

碳酸盐化橄榄岩的电性研究   总被引：3，自引：1，他引：2       下载免费PDF全文

黄小刚  黄晓葛  白武明 《地球物理学报》2012,55(9):3144-3151

为进一步探讨上地幔的高导层成因,了解碳酸盐在上地幔电性方面的作用并估算上地幔高导层的碳酸盐含量,本文对不同碳酸盐含量的橄榄岩及玄武岩样品在2~3 GPa、300~1300℃的条件下进行了电性实验研究.研究初步发现:碳酸盐熔体显著增强橄榄岩、玄武岩样品的导电能力;单纯用含硅酸盐熔体的橄榄岩或单纯用含水橄榄岩可能难以解释上地幔某些区域的异常高导现象;同样,单纯用碳酸盐化的橄榄岩可能也难以解释上地幔某些区域的高导现象;上地幔的高导区很可能是碳酸盐熔体、硅酸盐熔体及水的共存区域.  相似文献   

内蒙古维拉斯托锌铜矿床选矿试验研究     

常帼雄  刘宏伟  郭义平 《地质与资源》2011,20(6):434-439

维拉斯托锌铜多金属矿床矿石中富含多种元素,其中铜、铅、锌、砷、银、钨、钴等元素具有综合利用价值,矿石类型属于比较难选多金属矿石.采用混合浮选铜铅（-0.076 mm为65%）-依次浮选锌、砷（钴）-再浮选钨-重选（摇床）选钨的选矿工艺流程,对选矿pH值、药剂种类及用量等系列选矿条件进行了实验研究,达到较为理想的选矿效果,为矿山生产提供了技术保证.  相似文献   

Influence of igneous processes and serpentinization on geochemistry of the Logatchev Massif harzburgites (14°45′N,Mid-Atlantic Ridge), and comparison with global abyssal peridotites     

《International Geology Review》2012,54(1):115-130

We acquired bulk-rock analyses of Mid-Atlantic Ridge (MAR) harzburgites in order to understand the influence of submarine igneous and metamorphic processes on the distribution of incompatible elements (especially rare Earth elements or REEs) in abyssal peridotites. The geochemical characteristics of these Logatchev Massif serpentinized and talc-altered harzburgites, and spatially associated metagabbros were then compared with a compilation of global abyssal peridotites. The Logatchev harzburgites show light rare earth element (LREE) enrichments (average La _N /Yb _N = 2.81), positive correlations between LREEs (e.g. La, Ce, Pr, and Nd) and high field strength elements (HFSEs; e.g. Nb and Zr), and positive correlations between HFSEs and Th. Most global abyssal peridotites show similar trends. We suggest that the systematic enrichment of incompatible elements probably reflects a post-partial fusion magmatic refertilization. The compositional scatter exhibited by some serpentinized peridotites in Nb-LREE diagrams is probably due to the elimination of diopside during partial melting and significant impregnation by a melt produced in the Opx–Ol–Sp melting field rather than to later hydrothermal alteration. The correlation between Pb and Nd observed for most global abyssal peridotites, including the Logatchev harzburgites, indicates magmatic generation. The scatter of Pb in some rocks suggests that lead is likely mobile during serpentinization or weathering. Low to moderate water/rock (W/R) ratios in the harzburgites calculated from Sr isotopic compositions (5.98–26.20 for a close system and 1.66–2.72 for an open system), and the low abundance of REEs in Logatchev hydrothermal fluids indicate that the REE contents of abyssal peridotites probably were little influenced by hydrothermal alteration. Compared to this later alteration, the presence of small proportions of gabbroic melt (from 1:30 to 1:3 in our sample) that crystallized in the residual harzburgites modified their REE patterns significantly by elevating the LREEs.  相似文献   

Subduction of a fossil slow–ultraslow spreading ocean: a petrology-constrained geodynamic model based on the Voltri Massif,Ligurian Alps,Northwest Italy     

《International Geology Review》2012,54(7):787-803

Slow–ultraslow spreading oceans are mostly floored by mantle peridotites and are typified by rifted continental margins, where subcontinental lithospheric mantle is preserved. Structural and petrologic investigations of the high-pressure (HP) Alpine Voltri Massif ophiolites, which were derived from the Late Jurassic Ligurian Tethys fossil slow–ultraslow spreading ocean, reveal the fate of the oceanic peridotites/serpentinites during subduction to depths involving eclogite-facies conditions, followed by exhumation.

The Ligurian Tethys was formed by continental extension within the Europe–Adria lithosphere and consisted of sea-floor exposed mantle peridotites with an uppermost layer of oceanic serpentinites and of subcontinental lithospheric mantle at the rifted continental margins. Plate convergence caused eastward subduction of the oceanic lithosphere of the Europe plate and the uppermost serpentinite layer of the subducting slab formed an antigorite serpentinite-subduction channel. Sectors of the rather unaltered mantle lithosphere of the Adria extended margin underwent ablative subduction and were detached, embedded, and buried to eclogite-facies conditions within the serpentinite-subduction channel. At such P–T conditions, antigorite serpentinites from the oceanic slab underwent partial HP dehydration (antigorite dewatering and growth of new olivine). Water fluxing from partial dehydration of host serpentinites caused partial HP hydration (growth of Ti-clinohumite and antigorite) of the subducted Adria margin peridotites. The serpentinite-subduction channel (future Beigua serpentinites), acting as a low-viscosity carrier for high-density subducted rocks, allowed rapid exhumation of the almost unaltered Adria peridotites (future Erro–Tobbio peridotites) and their emplacement into the Voltri Massif orogenic edifice. Over in the past 35 years, this unique geologic architecture has allowed us to investigate the pristine structural and compositional mantle features of the subcontinental Erro–Tobbio peridotites and to clarify the main steps of the pre-oceanic extensional, tectonic–magmatic history of the Europe–Adria asthenosphere–lithosphere system, which led to the formation of the Ligurian Tethys.

Our present knowledge of the Voltri Massif provides fundamental information for enhanced understanding, from a mantle perspective, of formation, subduction, and exhumation of oceanic and marginal lithosphere of slow–ultraslow spreading oceans.  相似文献   

Petrology and geochemistry of prograde deserpentinized peridotites from Happo-O’ne, Japan: Evidence of element mobility during deserpentinization     

Mohamed Zaki Khedr  Shoji Arai 《Journal of Asian Earth Sciences》2012,43(1):150-163

The prograde deserpentinized peridotites from the talc zone in the Happo-O’ne complex, central Japan, show differences in their field relation and mineral assemblage with the high-P retrograde peridotites of the other part of the complex. They show a mineral assemblage, olivine + talc + antigorite ± prograde tremolite ± chlorite, formed by thermal metamorphism around the granitic intrusion at T, 500-650 °C and P < 7 kbar. The olivine has numerous opaque inclusions and high Fo (91.5-96.5) relative to the retrograde olivine, reflecting its formation by deserpentinization. The prograde tremolite, which is low in Al₂O₃ (<1.0 wt.%), Cr₂O₃ (<0.35 wt.%), and Na₂O (<0.6 wt.%) but high in Mg# (up to 0.98) and SiO₂ (up to 59.9 wt.%), is different in size, shape and chemistry from the retrograde tremolite. The prograde peridotites display a U-shaped REE pattern (0.02-0.5 times PM), similar to diopside-zone retrograde metaperidotites, possible protoliths. They are enriched in LILE (e.g., Cs, Pb, Sr, Rb) relative to HFSE (e.g., Ta, Hf, Zr, Nb), like their protoliths, because of their local re-equilibration with the fluid released during dehydration of the protoliths. They have high contents of REE and some trace elements (e.g., Cs, Th, U, Ta) relative to their protoliths because of an external-element addition from the granitic magma. In-situ analyses of peridotitic silicates confirmed that the prograde tremolite and talc display a spoon-shaped primitive mantle (PM)-normalized REE pattern (0.1-3 times PM) in which LREE are higher than HREE contents. The prograde tremolite is depleted in Al, Na, Cr, Sc, V, Ti, B, HREE and Li, but is enriched in Si, Cs, U, Th, HFSE (Hf, Zr, Nb, Ta), Rb and Ba relative to the retrograde tremolite; the immobile-element depletion in this tremolite is inherited from its source (antigorite + secondary diopside), whereas the depletion of mobile elements (e.g., Li, B, Na, Al) is ascribed to their mobility during the deserpentinization and/or the depleted character of the source of tremolite. The enrichment of HFSE and LILE in the prograde tremolite is related to an external addition of these elements from fluid/melt of the surrounding granitic magma and/or in situ equilibrium with LILE-bearing fluid released during dehydration of serpentinized retrograde metaperidotites and olivine-bearing serpentinites (protoliths). The prograde olivine is higher in REE and most trace-element contents than the retrograde one due to the external addition of these elements; it is enriched in B, Co and Ni, but depleted in Li that was liberated during deserpentinization by prograde metamorphism.  相似文献   

辉南新生代玄武岩中捕虏体橄榄岩矿物化学与华北岩石圈地幔演化     

鲁江姑  郑建平 《地质学报》2011,85(3):330-342

内容提要：在对吉林辉南新生代玄武岩中捕虏体橄榄岩详细的岩相学和矿物主量元素研究基础上,重点分析了单斜辉石激光原位微量元素,并讨论了辉南陆下岩石圈地幔的性质及其在华北克拉通破坏过程中的意义。橄榄石、单斜辉石和尖晶石的Mg#和Cr#均表明该区陆下岩石圈地幔主体是饱满的,同时也存在少量过渡和难熔型地幔。单斜辉石REE配分形式包括LREE亏损、倒U字型REE和LREE富集等不同类型。这些橄榄岩是地幔经历不同程度的部分熔融作用(低于10%)和复杂地幔交代作用的产物。交代介质主体是硅酸盐熔体,但个别样品有碳酸岩熔体交代的残留。橄榄石Mg#和平衡温度无相关性,说明辉南陆下岩石圈地幔不存在明显的分层而是交叉的。这些地幔特征和华北东部其他地区新生代的主体地幔性质相似,是熔-岩反应、侵蚀作用和上涌软流圈物质冷却转变置换的综合结果。  相似文献